A FACILE SYNTHESIS OF NEW TETRAPYRROLE MACROCYCLIC DERIVATIVES - FORMATION OF BIMETALLIC TRANSITION-METAL COMPLEXES

被引：47

作者：

CORRIU, RJP

BOLIN, G

MOREAU, JJE

VERNHET, C

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/c39910000211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Me(hexynyl)CuLi with (Me3Si)2NCH2-C=C-CO2Et followed by treatment with a diacid dichloride gave a facile access to meta-dipyrrolyl benzene or 2,6-dipyrrolyl pyridine derivatives, which were cyclised to tetrapyrrolic macrocycles 7 and 9; further reactions with Pd(acac)2 or Ni(acac)2 led to bimetallic complexes.

引用

页码：211 / 213

页数：3

共 25 条

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