A 1,2-PHENYLENE-BRIDGED PORPHYRIN DIMER - SYNTHESIS, PROPERTIES, AND MOLECULAR-STRUCTURE

被引：101

作者：

OSUKA, A ^{[1
]}

NAKAJIMA, S ^{[1
]}

NAGATA, T ^{[1
]}

MARUYAMA, K ^{[1
]}

TORIUMI, K ^{[1
]}

机构：

[1] OKAZAKI NATL RES INST,INST MOLEC SCI,OKAZAKI 444,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 05期

关键词：

D O I：

10.1002/anie.199105821

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The porphyrin rings in the porphyrin dimer 1 are nearly planar, but they are considerably tilted toward each other. Compound 1 is of interest as a model for the special pair of the photosynthetic reaction center. The average distance between the two porphyrin planes is only 3.43 angstrom. The resulting strong interactions-resembling those in excimers-lead to a lowering of the energy of the S1 state and facilitate one-electron oxidation.

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页码：582 / 584

页数：3

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