EFFECT OF ADDITION OF SACCHAROSE ON GELATION OF AQUEOUS POLY(VINYL ALCOHOL) SOLUTIONS

被引:10
作者
YAMAURA, K [1 ]
MITSUISHI, M [1 ]
FUKUDA, M [1 ]
TANIGAMI, T [1 ]
HOEI, Y [1 ]
MATSUZAWA, S [1 ]
机构
[1] S&S JAPAN CO LTD,NAGATA KU,KOBE,HYOGO 653,JAPAN
关键词
D O I
10.1002/app.1995.070560602
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The properties of poly(vinyl alcohol) (PVA) hydrogels containing saccharose were examined. The effect of the addition of saccharose to atactic PVA (a-PVA) gels on their melting temperatures was larger than that for syndiotacticity-rich PVA (s-PVA) gels and the melting temperature was above 100 degrees C for a-PVA gels with saccharose contents of 60 wt %. However, the fusion enthalpy (Delta H) of the a-PVA gels was at most 100 kJ/mol. The release of solvent (water/saccharose) from gels in air decreased with an increase in the saccharose content and the equilibrium was achieved after standing for 20 days for the a-PVA and s-PVA gels with saccharose contents above 40 and 20 wt %, respectively. (C) 1995 John Wiley and Sons, Inc.
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页码:653 / 659
页数:7
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