CONVENIENT SYNTHESIS OF TRIMETHYLSILYLDIAZOMETHANE - SILENE GENERATOR

被引：19

作者：

BARTON, TJ

HOEKMAN, SK

机构：

[1] Department of Chemistry, Iowa State University, Ames, Iowa

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1979年 / 9卷 / 04期

关键词：

D O I：

10.1080/00945717908069745

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metallation of chloromethyltrimethylsilane followed by reaction of the resulting carbanion and tosyl azide produces trimethylsilyldiazomethane in 38 percent yield. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：297 / 300

页数：4

共 7 条

[1] BARTON TJ, 1978, 5TH INT S ORG CHEM K
[2] 1,1,2-TRIMETHYLSILAETHYLENE
CHAPMAN, OL
CHANG, CC
KOLC, J
JUNG, ME
LOWE, JA
BARTON, TJ
TUMEY, ML
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (24) : 7844 - 7846
[3] SOLID-STATE CHEMISTRY - DISCRETE TRIMETHYLSILYLMETHYLENE
CHEDEKEL, MR
SKOGLUND, M
KREEGER, RL
SHECHTER, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (24) : 7846 - 7848
[4] DIMROTH O, 1910, J LIEBIGS ANN CHEM, V373, P336
[5] DIAZOCYCLOPENTADIENE
DOERING, WV
DEPUY, CH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (23) : 5955 - 5957
[6] KREEGER RL, 1975, TETRAHEDRON LETT, P2061
[7] TRIMETHYLSILYL-SUBSTITUTED DIAZOALKANES .1. TRIMETHYLSILYLDIAZOMETHANE
SEYFERTH, D
DOW, AW
MENZEL, H
FLOOD, TC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 44 (02) : 279 - &

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