TETRACYCLOPENTADIENYLTITANIUM(IV) AND TRICYCLOPENTADIENYLTITANIUM(III)

被引：46

作者：

SIEGERT, FW

MEIJER, HJD

机构：

[1] Laboratorium voor Anorganische Chemie, Rijksuniversiteit, Groningen

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 20卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)80098-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and properties of the complexes (C5H5)4Ti and (C5H5)3Ti are described. IR and NMR spectra show that these complexes have the structures (π-C5H5)2Ti(σ-C5H5)2 and (π-C5H5)2Ti(σ-C5H5) respectively. The spectra and properties of the two compounds are compared with those of (π-C5H5)2Nb(σ-C5H5)2 and (π-C5H5)2V(σ-C5H5). The compound (π-C5H5)2V(σ-C5H5)2 could not be prepared. © 1969.

引用

页码：141 / &

共 11 条

[1] BREEDERVELD H, 1963, Patent No. 3089886
[2] FISCHER EO, 1960, Z NATURFORSCH PT B, V15, P266
[3] UBER AROMATENKOMPLEXE VON METALLEN .45. UBER TETRACYCLOPENTADIENYLE DES NIOBS UND TANTALS
FISCHER, EO
TREIBER, A
[J]. CHEMISCHE BERICHTE-RECUEIL, 1961, 94 (08): : 2193 - 2197
[4] INFRARED AND RAMAN SPECTRAL STUDIES OF PI-COMPLEXES FORMED BETWEEN METALS AND CNHN RINGS
FRITZ, HP
[J]. ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1964, 1 : 239 - 316
[5] MEIJER HJD, 1967, 3 INT S ORG CHEM MUN, P250
[6] A METAL CARBONYL COMPOUND OF TITANIUM
MURRAY, JG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (06) : 1287 - &
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[10] SIEGERT FW, 1969, 4 INT C ORG CHEM BRI

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