DIISOPROPYLAMINOMETHYLIDYNE COMPLEXES OF IRON, CHROMIUM, MOLYBDENUM AND TUNGSTEN

被引：18

作者：

ANDERSON, S ^{[1
]}

HILL, AF ^{[1
]}

机构：

[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 394卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(90)87274-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [M(CO)n] (n = 6, M = Cr, Mo, W; n = 5, M = Fe) successively with LiNiPr2, (CF3CO)2O, and PPh3 leads to the thermally stable diisopropylaminomethylidyne complexes [M(CNiPr2)(O2CCF3)(CO)3(PPh3)] (M = Cr, Mo, W) and [Fe(CNiPr2)(O2CCF3)(CO)2(PPh3)] in high yield. The latter is the first neutral mononuclear carbyne complex of iron. © 1990.

引用

页码：C24 / C26

页数：3

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