PENTADIENYL-METAL PHOSPHINE CHEMISTRY .26. PHOSPHAPENTADIENYL-IRIDIUM-PHOSPHINE CHEMISTRY - SYNTHESIS, STRUCTURE, AND SPECTROSCOPY OF (MU-ETA-1-PHOSPHAPENTADIENYL)2IR2(PET3)4

被引：18

作者：

BLEEKE, JR

ROHDE, AM

ROBINSON, KD

机构：

[1] Department of Chemistry, Washington University, St. Louis

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1021/om00014a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of an anionic phosphapentadienide reagent, lithium phosphapentadienide has been isolated and spectroscopically characterized. Reaction of this species with (Cl)Ir(PEt3)3 yielded the phosphido-bridged iridium dimer (mu-eta1-phosphapentadienyl)2Ir2(PEt3)4 as trans and cis isomers (1a and 1b, respectively). An X-ray crystal structure of 1a has been obtained.

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页码：401 / 403

页数：3

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