HAMMETT REACTION CONSTANT FOR A TERMINAL METHOXYPHOSPHINIDENE COMPLEX - ABSENCE OF AMBIPHILICITY

被引：15

作者：

WANG, B ^{[1
]}

LAMMERTSMA, K ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,BIRMINGHAM,AL 35294

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1994年 / 116卷 / 23期

关键词：

D O I：

10.1021/ja00102a015

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Hammett reaction constant rho(+) has been determined for the styrene addition of MeO-P-W(CO)(5), as generated from the appropriate 7-phosphanorbornadiene complex. The phosphinidene reactivity is evaluated and compared with that of the ambiphilic MeO-C-Cl carbene.

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页码：10486 / 10488

页数：3

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