A NOVEL RH-B SIGMA-BOND - CRYSTAL-STRUCTURE OF [N(CH3)4][RHCL(7,8-MU-S(CH2CH2)S-C2B9H10)(SIGMA-7,8-MU-S(CH2CH2)S-C2B9H9)]

被引：30

作者：

TEIXIDOR, F ^{[1
]}

ROMEROSA, A ^{[1
]}

VINAS, C ^{[1
]}

RIUS, J ^{[1
]}

MIRAVITTLES, C ^{[1
]}

CASABO, J ^{[1
]}

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 03期

关键词：

D O I：

10.1039/c39910000192

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [N(CH3)4][RhCl{7,8-mu-S(CH2CH2)S-C2B9H10}{sigma-7,8-mu-S(CH2CH2)S-C2B9H9}] is an octahedral Rh(iii) complex; the sixth coordination site is occupied by a sigma-bond B-Rh in this first example of B(3)-Rh coordination.

引用

页码：192 / 193

页数：2

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