1-ALKYL-4-FLUORO-1,4-DIAZONIABICYCLO[2.2.2]OCTANE SALTS - A NOVEL FAMILY OF ELECTROPHILIC FLUORINATING AGENTS

被引：237

作者：

BANKS, RE ^{[1
]}

MOHIALDINKHAFFAF, SN ^{[1
]}

LAL, GS ^{[1
]}

SHARIF, I ^{[1
]}

SYVRET, RG ^{[1
]}

机构：

[1] AIR PROD & CHEM INC,CTR CORP SCI & TECHNOL,ALLENTOWN,PA 18195

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 08期

关键词：

D O I：

10.1039/c39920000595

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Members of a new series of solid, easily handled, storable, transportable, commercially viable, site-selective electrophilic fluorinating agents of the +N-F class (tradenamed Selectfluor reagents) have been synthesized via direct fluorination of monoquaternary salts of 1,4-diazabicyclo[2.2.2]octane.

引用

页码：595 / 596

页数：2

共 17 条

[1] N-HALOGENO-COMPOUNDS .10. N-FLUOROQUINUCLIDINIUM TRIFLATE [J].

BANKS, RE ;

SHARIF, I .

JOURNAL OF FLUORINE CHEMISTRY, 1988, 41 (02) :297-300

[2] N-HALOGENO COMPOUNDS .9. N-FLUOROQUINUCLIDINIUM FLUORIDE - A NEW ELECTROPHILIC FLUORINATING AGENT [J].

BANKS, RE ;

DUBOISSON, RA ;

MORTON, WD ;

TSILIOPOULOS, E .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (10) :2805-2811

[3] N-HALOGENO COMPOUNDS .12. SITE-SPECIFIC FLUORINATION OF CARBANIONS WITH PERFLUORO-N-FLUOROPIPERIDINE [J].

BANKS, RE ;

MURTAGH, V ;

TSILIOPOULOS, E .

JOURNAL OF FLUORINE CHEMISTRY, 1991, 52 (03) :389-401

[4]

BANKS RE, 1991, J FLUORINE CHEM, V54, P207

[5]

BANKS RE, UNPUB

[6]

BANKS RE, 1986, THESIS U MANCHESTER

[7]

BANKS RE, 1992, J FLUORINE CHEM, V55, P207

[8]

FURIN GG, 1989, NEW FLUORINATING AGE, P34

[9]

Kilbourn M. R., 1990, FLUORINE 18 LABELING

[10]

MUKAMETSHIN FM, 1989, NEW FLUORINATING AGE, P59

← 1 2 →