PREPARATION OF SURFACE MODIFIED CDS MICROCRYSTALLITES - ENHANCEMENT OF SOLUBILITY IN ALCOHOLS BY CAPPING WITH PENTAFLUOROTHIOPHENOL

被引：15

作者：

OGATA, T

HOSOKAWA, H

OSHIRO, T

WADA, Y

SAKATA, T

MORI, H

YANAGIDA, S

机构：

[1] OSAKA UNIV, FAC ENGN, SUITA, OSAKA 565, JAPAN

[2] OSAKA UNIV, ULTRA HIGH VOLTAGE ELECTRON MICROSCOPY RES CTR, IBARAKI, OSAKA 567, JAPAN

[3] NIPPON MEKTRON LTD, INASHIKI, IBARAKI 30012, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 09期

关键词：

D O I：

10.1246/cl.1992.1665

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pentafluorophenyl-capped CdS microcrystallites (av. 3-6 nm in diameter) are prepared and characterized by TEM and F-19 NMR spectroscopy. Although the similarly prepared phenyl-capped CdS microcrystallites is insoluble in alcohols, the capping with perfluorinated phenyl groups induces high solubility in methanol and ethanol.

引用

页码：1665 / 1666

页数：2

共 5 条

[1] SYNTHESIS AND CHARACTERIZATION OF SURFACE-CAPPED, SIZE-QUANTIZED CDS CLUSTERS - CHEMICAL CONTROL OF CLUSTER SIZE [J].