A NOVEL AND CONVENIENT METHOD FOR PALLADIUM-CATALYZED ALKOXYCARBONYLATION OF ARYL AND VINYL HALIDES USING HCO2R/NAOR SYSTEM

被引：82

作者：

CARPENTIER, JF ^{[1
]}

CASTANET, Y ^{[1
]}

BROCARD, J ^{[1
]}

MORTREUX, A ^{[1
]}

PETIT, F ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM LILLE,CNRS,CHIM ORGAN APPL LAB,BP 108,F-59652 VILLENEUVE DASCQ,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 36期

关键词：

ALKOXYCARBONYLATION; ESTER; FORMATE; PALLADIUM;

D O I：

10.1016/S0040-4039(00)92287-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl iodides, vinyl bromides and tricarbonyl(chloroarene)chromium complexes react under mild conditions with sodium alkoxides and alkyl formates as source of carbon monoxide in the presence of dichlorobis(triphenylphosphine)palladium as catalyst to give the corresponding carboxylic esters in high yields.

引用

页码：4705 / 4708

页数：4

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