ELECTROCHEMICAL OXIDATION OF N-METHYLATED DERIVATIVES OF URIC-ACID

被引：34

作者：

WRONA, MZ ^{[1
]}

OWENS, JL ^{[1
]}

DRYHURST, G ^{[1
]}

机构：

[1] UNIV OKLAHOMA,DEPT CHEM,NORMAN,OK 73019

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 105卷 / 02期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0022-0728(79)80124-2

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The electrochemical oxidation of a number of N-methylated uric acids has been studied by linear and cyclic sweep voltammetry, coulometry and thin-layer spectroelectrochemistry. The observed results support the view that the electrooxidation is a 2e reaction to give a very unstable diimine primary product. This is rapidly hydrated to give an imine-alcohol which is further hydrated to give a uric acid-4,5-diol derivative which subsequently fragments to the various products. © 1979 Elsevier Sequoia S.A.

引用

页码：295 / 315

页数：21

共 16 条

[1] THE RELATIONSHIP BETWEEN SPECTRAL SHIFTS AND STRUCTURAL CHANGES IN URIC ACIDS AND RELATED COMPOUNDS [J].