5-COORDINATION IN PLATINUM(II) SPECIES - WHEN AND WHY

被引：84

作者：

FANIZZI, FP

MARESCA, L

NATILE, G

LANFRANCHI, M

TIRIPICCHIO, A

PACCHIONI, G

机构：

[1] CNR,CHIM GEN & INORGAN,I-43100 PARMA,ITALY

[2] CNR,CTR STUDIO STRUTT DIFFRATTOMETR,I-43100 PARMA,ITALY

[3] UNIV MILAN,CNR,DIPARTIMENTO CHIM INORGAN & MET ORGAN,I-20133 MILAN,ITALY

[4] UNIV MILAN,CTR CNR,I-20133 MILAN,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 04期

关键词：

D O I：

10.1039/c39920000333

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ground state geometry of the platinum(II) complexes [Pt(N-N)(L)X2] (N-N = bidentate N-donor ligand; L, X = monodentate ligands) becomes five-coordinate trigonal-bipyramidal whenever a strong pi-accepting ligand (L) is present in the coordination sphere, in absence of it even a rigid phenanthroline acts as monodentate ligand and the complex is four-coordinate.

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页码：333 / 335

页数：3

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