SYNTHESIS OF CADMIUM-SULFIDE INSITU IN CADMIUM BIS(ETHYL-2-HEXYL) SULFOSUCCINATE REVERSE MICELLE - POLYDISPERSITY AND PHOTOCHEMICAL-REACTION

被引:129
作者
MOTTE, L
PETIT, C
BOULANGER, L
LIXON, P
PILENI, MP
机构
[1] CENS,DRECAM,SCM,F-91191 GIF SUR YVETTE,FRANCE
[2] CENS,CEREM,DTM,SRMP,F-91191 GIF SUR YVETTE,FRANCE
[3] UNIV PARIS 06,LAB SRI BATIMENT CHIM PHYS,F-75230 PARIS 05,FRANCE
关键词
D O I
10.1021/la00040a006
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Functionalized reverse micelles are used to control the size of CdS semiconductor particles. We show that the use of mixed sodium-cadmium AOT reverse micelles favors the formation of monodispersed particles. By increase of the water content, the size of the particle increases, maintaining a high monodispersity. Photoelectron transfer reactions are more efficient at smaller particle size than at higher. At low water content, CdS semiconductors are protected against photocorrosion.
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页码:1049 / 1053
页数:5
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