SUPRAMOLECULAR LIQUID-CRYSTALLINE COMPLEXES EXHIBITING ROOM-TEMPERATURE MESOPHASES AND ELECTROOPTIC EFFECTS - HYDROGEN-BONDED MESOGENS DERIVED FROM ALKYLPYRIDINES AND BENZOIC-ACIDS

被引:130
作者
KATO, T
FUKUMASA, M
FRECHET, JMJ
机构
[1] JAPAN ENERGY CORP,PETR LAB,TODA,SAITAMA 335,JAPAN
[2] CORNELL UNIV,BAKER LAB,DEPT CHEM,ITHACA,NY 14853
关键词
D O I
10.1021/cm00050a021
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrogen-bonded liquid-crystalline complexes containing only two aromatic rings have been designed and obtained through 1:1 (molar ratio) complexation of 4-alkoxy- or 4-alkylbenzoic acid (nOBA or nBA; n is the carbon number of the alkyl group) and 4-octyl- or 4-undecylpyridine (8Py or 11Py). These supramolecular H-bonded complexes exhibit stable mesophases in the vicinity of room temperature. For a series of complexes obtained from nOBA and 8Py, only nematic phases are observed near room temperature. For example, the 1:1 complex obtained from an equimolar amount of 4-hexyloxybenzoic acid and 4-octylpyridine (6OBA-8Py) exhibits a nematic phase from 38 to 48 degrees C. In contrast, for a series of complexes from nBA and 8Py, only smectic phases are seen at room temperature. For example, 6BA-8Py shows a smectic A phase from 29 to 33 degrees C. On cooling, the smectic A phase appears at 33 degrees C and a subsequent smectic C phase is observed from 13 to 10 degrees C. The effects of lateral substituents on the liquid-crystalline behavior have been examined for 6OBA-8Py system using 3-chloro and 3-fluoro-4-hexyloxybenzoic acids as H-bond donors. The use of these substituents depresses the isotropization temperature and also induces smectic phases for the complexes. The mesophase range has been extended by the mixing of complexes because of the resulting depression of melting points. A mixture of nematogenic complexes can be aligned on a rubbed surface and shows electrooptic effects in a twisted nematic cell.
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页码:368 / 372
页数:5
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