AN ANALOG COMPUTER STUDY OF POLYMERIZATION RATES IN VINYL CHLORIDE SUSPENSIONS

An analog computer‐polymerizer system is described which polts continually the rate of polymerization in percent per hour and the total percent conversion. Computer components and their functions are briefly described and the polymerization vessel with its control instruments are shown. Methods of calibration and accuracy of the system are discussed. Polymerization rate curves for various initiators at various temperatures are presented. These curves show the typical autoacceleration of precipitating systems and the rate increase due to the gel effect. Experimental evidence is presented to explain the pressure drop seen in these curves at 70–75% conversion. Copyright © 1969 Society of Plastics Engineers, Inc.