FLASH THERMOLYSIS OF GAMMA-SULTINES

被引：10

作者：

DURST, T ^{[1
]}

FINLAY, JD ^{[1
]}

SMITH, DJH ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 04期

关键词：

D O I：

10.1039/p19790000950

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The flash thermolysis of 1,2-oxathiolan 2-oxides (1) has been shown to lead to a mixture of cyclopropanes and alkenes. When a stabilising group is present at the 5-position as in (1a) and (1b) only cyclopropanes are obtained.

引用

页码：950 / 952

页数：3

共 13 条

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[2] PHOTO-CHEMICAL EXTRUSION OF SULFUR-DIOXIDE FROM SULTINES
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[3] FINLAY JD, 1977, TETRAHEDRON LETT, P1149
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[5] HALES NJ, 1976, J CHEM SOC CHEM COMM, P981, DOI 10.1039/c39760000981
[6] Hedaya E., 1970, J AM CHEM SOC, V92, P2149
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SHARMA, NK
DURST, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (10) : 3420 - 3422
[8] STEREOCHEMICAL CONSEQUENCES OF ORBITAL SYMMETRY CONTROL IN REVERSIBLE COMBINING OF SULFUR-DIOXIDE WITH CONJUGATED SYSTEMS (SULFOLENE REACTIONS)
MOCK, WL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (13) : 3666 - 3672
[9] SYNTHESIS OF SULTINES VIA TERT-BUTYL HYDROXYALKYL SULFOXIDES
SHARMA, NK
DEREINACHHIRTZBACH, F
DURST, T
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1976, 54 (19): : 3012 - 3020
[10] TRANSANULAR INTERACTIONS IN [2.2]PHANES .2. SYNTHESES OF [2.2](4,4')BIPHENYLOPHANE, [2.2](2,7)PHENANTHRENOPHANE AND [2](4,4')BIPHENYLO[2](2,7)PHENANTHRENOPHANE
STAAB, HA
HAENEL, M
[J]. CHEMISCHE BERICHTE-RECUEIL, 1973, 106 (07): : 2190 - 2202

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