WACKER OXIDATION CATALYSIS IN A SUPPORTED AQUEOUS PHASE

被引：36

作者：

ARHANCET, JP

DAVIS, ME

HANSON, BE

机构：

[1] CALTECH,DEPT MECH ENGN,PASADENA,CA 91125

[2] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

CATALYSIS LETTERS | 1991年 / 11卷 / 02期

关键词：

WACKER OXIDATION CATALYSIS; SUPPORTED AQUEOUS PHASE; (SAP) CATALYSIS;

D O I：

10.1007/BF00764078

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Adsorption of palladium (II) and copper (II) salts onto the controlled pore glass CPG-240, in the presence of water, yields a supported aqueous phase Wacker oxidation catalyst. Conversions of 1-heptene to 2-heptanone of up to 24% under batch conditions are observed. The activity and selectivity of the catalysts are sensitive to water content, oxygen pressure and temperature.

引用

页码：129 / 136

页数：8

共 14 条

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