USE OF ALUMINUM AS AN ELECTRON POOL - REDUCTIVE COUPLING OF IODOBENZENES PROMOTED BY ELECTRON-TRANSFER IN AN NI/PB/AL MULTI-REDOX SYSTEM

被引：10

作者：

TANAKA, H ^{[1
]}

SUMIDA, S ^{[1
]}

KOBAYASHI, N ^{[1
]}

KOMATSU, N ^{[1
]}

TORII, S ^{[1
]}

机构：

[1] OKAYAMA UNIV,FAC ENGN,DEPT APPL CHEM,OKAYAMA 700,JAPAN

来源：

INORGANICA CHIMICA ACTA | 1994年 / 222卷 / 1-2期

关键词：

REDUCTIVE COUPLING OF IODOBENZENES; ALUMINUM COMPLEXES; NICKEL COMPLEXES; LEAD COMPLEXES; ELECTRON TRANSFER CATALYST; MULTI-METAL REDOX SYSTEM;

D O I：

10.1016/0020-1693(94)03924-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reductive coupling of iodobenzenes was achieved successfully by use of a stoichiometric amount of aluminium metal as an electron source and catalytic amounts of NiCl2(bpy) (bpy = 2,2'-bipyridyl) and lead(II) bromide as electron transfer catalysts in methanol containing potassium iodide.

引用

页码：323 / 325

页数：3

共 22 条

[1]

DHIMANE H, 1990, B SOC CHIM FR, V127, P283

[2] PRENYLATION OF QUINONOID COMPOUNDS WITH PRENYL BROMIDE USING LEAD BROMIDE ALUMINUM POWDER AS CATALYST [J].

KHANNA, RN ;

SINGH, PK .

SYNTHETIC COMMUNICATIONS, 1990, 20 (12) :1743-1749

[3] INTRAMOLECULAR ALLYLATION OF CARBONYL-COMPOUNDS - A NEW METHOD FOR 5 AND 6 MEMBERED RING FORMATION [J].

NOKAMI, J ;

WAKABAYASHI, S ;

OKAWARA, R .

CHEMISTRY LETTERS, 1984, (06) :869-870

[4] AL-NICL2.6H2O-THF - A NEW, MILD AND NEUTRAL SYSTEM FOR SELECTIVE REDUCTION OF ORGANIC FUNCTIONAL-GROUPS [J].

SARMAH, BK ;

BARUA, NC .

TETRAHEDRON, 1991, 47 (40) :8587-8600

[5]

SMITH M, 1968, REDUCTION TECHNIQUES, P95

[6] THE INSITU-GENERATED NICKEL(0)-CATALYZED REACTION OF ARYL HALIDES WITH POTASSIUM-IODIDE AND ZINC POWDER [J].

TAKAGI, K ;

HAYAMA, N ;

INOKAWA, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (12) :3691-3695

[7] NI(0)-TRIALKYLPHOSPHINE COMPLEXES - EFFICIENT HOMO-COUPLING CATALYST FOR ARYL, ALKENYL, AND HETEROAROMATIC HALIDES [J].

TAKAGI, K ;

HAYAMA, N ;

SASAKI, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (07) :1887-1890

[8] REDUCTIVE DIMERIZATION OF ALLYL AND BENZYL HALIDES IN PB/NORMAL-BU4NBR-DMF AND PBBR2/AL-DMF SYSTEMS [J].

TANAKA, H ;

YAMASHITA, S ;

TORII, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (05) :1951-1953

[9] A NOVEL TI(0) INDUCED ALLYLATION OF IMINES IN A TICL4 (CAT) AL BIMETAL SYSTEM - CHIRALITY TRANSFER OF L-VALINE TO HOMOALLYLAMINE [J].

TANAKA, H ;

INOUE, K ;

POKORSKI, U ;

TANIGUCHI, M ;

TORII, S .

TETRAHEDRON LETTERS, 1990, 31 (21) :3023-3026

[10] REDUCTIVE ADDITION OF POLYHALOMETHANES AND THEIR RELATED-COMPOUNDS TO ALDEHYDES AND 1,2-ELIMINATION OF THE COUPLING PRODUCTS IN A PB/AL BIMETAL REDOX SYSTEM [J].

TANAKA, H ;

YAMASHITA, S ;

YAMANOUE, M ;

TORII, S .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (02) :444-450

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