INTRAMOLECULAR BONDING IN BETA-SILYL KETONES

被引：24

作者：

PEDDLE, GJD

机构：

[1] Department of Chemistry, University of Alberta, Edmonton, Alta.

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 14卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)92646-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A comparison of the infrared carbonyl group absorption of 2-(triphenylsilyl)cyclohexanone and of 2-(triphenylmethyl)cyclohexanone provided evidence of intramolecular interaction between the silicon atom and the carbonyl group. A similar interaction was found in the analogous 2-(triphenylsilyl)- and 2-(triphenylgermyl)cyclohexanols. © 1968.

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页码：115 / &

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