KINETICS OF THE CHLORINATION OF BIPHENYL UNDER CONDITIONS OF WASTE TREATMENT PROCESSES

被引：18

作者：

SNIDER, EH ^{[1
]}

ALLEY, FC ^{[1
]}

机构：

[1] CLEMSON UNIV,DEPT CHEM ENGN,CLEMSON,SC 29631

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1979年 / 13卷 / 10期

关键词：

D O I：

10.1021/es60158a016

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The chemical kinetics of the chlorination of low concentrations of biphenyl dissolved in water are presented. The pH range investigated was 6.2 to 9.0, in which range the chlorinating agent is molecular hypochlorous acid and its dehydration product, chlorine monoxide. The reactions in the neutral and alkaline ranges produced two monochlorobi-phenyls, o- and p-chlorobiphenyl, with a 1/2 o:p ratio of 0.8. Second-order dependence upon undissociated hypochlorous acid concentration and first-order dependence upon biphenyl concentration were observed. Reaction rate constants and activation energies were determined. Moderate ionic strength variations and potential metallic catalysts had no measurable influence on reaction rate. It was found that acid catalysis occurs below a pH of 6.2, where highly reactive molecular chlorine is present. © 1979, American Chemical Society. All rights reserved.

引用

页码：1244 / 1248

页数：5

共 36 条

[1] QUANTITATIVE AND QUALITATIVE ANALYSIS OF POLYCHLORINATED BIPHENYLS BY GAS-LIQUID CHROMATOGRAPHY AND FLAME IONIZATION DETECTION .1. ONE TO 3 CHLORINE ATOMS [J].