PHOSPHATE ADSORPTION AT THE POROUS-GLASS WATER AND SIO2/WATER INTERFACES

被引:16
作者
DALAS, E
KOUTSOUKOS, PG
机构
[1] DEPT CHEM,PHYS CHEM LAB,POB 1239,UNIV CAMPUS,GR-26110 PATRAS,GREECE
[2] RES INST CHEM ENGN & CHEM PROC HIGH TEMP,GR-26110 PATRAS,GREECE
关键词
D O I
10.1016/0021-9797(90)90139-F
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The adsorption of inorganic orthophosphate on porous glass and SiO2 surfaces has been investigated. Porous glass exhibited markedly higher affinity as compared to SiO2 toward phosphate, which was found to strongly depend on ionic strength and temperature. The phosphate uptake was relatively fast and the kinetics followed a simple first order equation. Adsorption data gave a satisfactory fit to a recently developed adsorption isotherm describing the adsorption of ions on heterogeneous surfaces, based on the classical Langmuir isotherm and assuming a Gaussian distribution of the free energies of adsorption. © 1990.
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页码:299 / 304
页数:6
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