PALLADIUM-CATALYZED CARBAMOYLATION AND ALKOXYCARBONYLATION OF VINYLORGANOTINS AND ARYLORGANOTINS - AN EASY ENTRY INTO VINYL OR ARYL AMIDES AND ESTERS

被引:35
作者
BALAS, L [1 ]
JOUSSEAUME, B [1 ]
SHIN, H [1 ]
VERLHAC, JB [1 ]
WALLIAN, F [1 ]
机构
[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,CNRS,URA 35,351 COURS LIBERAT,F-33405 TALENCE,FRANCE
关键词
D O I
10.1021/om00047a077
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The palladium-catalyzed cross-coupling reaction between substituted aryl- and vinylorganotins or heterocyclic organotin compounds and chloroformates or carbamoyl chlorides is reported. It proceeds smoothly to provide esters or amides in good yields. The reaction conditions are mild, and a wide range of functionalities on the tin reagent can be tolerated.
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页码:366 / 368
页数:3
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