STRUCTURE OF 1,1,1,2,2-PENTACARBONYL-MU-HYDRIDO-MU-2-ETA-[(Z,S-CIS,Z)-N-ISOPROPYL-CINNAMYLIDENEAMINO-MU-N,MU-C-GAMMA]-DIRUTHENIUM(RU-RU), HRU2(CO)5(C12H14N)

被引：5

作者：

SPEK, AL ^{[1
]}

DUISENBERG, AJM ^{[1
]}

MUL, WP ^{[1
]}

BEERS, OCP ^{[1
]}

ELSEVIER, CJ ^{[1
]}

机构：

[1] UNIV AMSTERDAM,JH VANT HOFF INST,ANORGAN CHEM LAB,1018 WV AMSTERDAM,NETHERLANDS

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190008769

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C17H15NO5Ru2, M(r) = 515.45, orthorhombic, Pcab, a = 12.828 (1), b = 16.813 (1), c = 34.324 (2) angstrom, V = 7402.9 (8) angstrom 3, Z = 16, D(x) = 1.85 g cm-3, lambda-(Mo K-alpha) = 0.71073 angstrom, mu = 16.3 cm-1, F(000) = 4032, T = 295 K, R = 0.038 for 5117 reflections with I > 2.5-sigma-(I). The two crystallographically independent molecules are essentially identical except for one torsion angle. The Ru-Ru bond is bridged asymmetrically by both a hydride atom and an N-isopropyl cinnamaldimin-4-yl ligand.

引用

页码：297 / 300

页数：4

共 13 条

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