REACTIVITY OF MAIN-GROUP TRANSITION-METAL BONDS .9. THE KINETICS OF IODINATION OF COMPOUNDS CONTAINING 2 OR MORE TIN TRANSITION-METAL BONDS

被引：9

作者：

CHIPPERFIELD, JR

CLARK, S

WEBSTER, DE

YUSOF, H

机构：

[1] Department of Chemistry, The University, Hull

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 421卷 / 2-3期

关键词：

D O I：

10.1016/0022-328X(91)86405-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rate coefficients are reported for the cleavage by halogens of tin-transition-metal bonds in compounds containing two or more such bonds. Bond reactivity with iodine is in the order Sn-Co almost-equal-to Sn-Fe > Sn-Mo almost-equal-to Sn-W > Sn-Mn. Rates of halogenation of compounds containing three tin-transition-metal bonds show that a subtle balance between steric and electronic effects determines bond reactivity.

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页码：205 / 213

页数：9

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