SYNTHESIS AND X-RAY STRUCTURE OF THE TRIANGULAR CLUSTER (ET4N)([MO3(MU-3-S)(MU-2-S2)3(NH2PH)3BR3]BR)BR

被引：31

作者：

FEDIN, VP

MIRONOV, YV

VIROVETS, AV

PODBEREZSKAYA, NV

FEDOROV, VY

机构：

[1] Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090

来源：

POLYHEDRON | 1992年 / 11卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)83165-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex of the formula (Et4N)Mo3S7Br5(NH2Ph)3 (1) has been prepared by interacting (Et4N)2Mo3S7Br6 with aniline. The crystal structure has been determined. The [Mo3S7(NH2Ph)3Br3] cation and two bromine anions form the ionic trimer due to the interaction of S...Br (2.93-3.32 angstrom) with three axial and one equatorial sulphur atoms of the mu-2-S2 ligands.

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页码：2083 / 2088

页数：6

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