FLUORESCENCE AND ABSORPTION-SPECTRA OF FROZEN AQUEOUS-SOLUTIONS OF GADOLINIUM SALTS

被引：18

作者：

COUTURE, L ^{[1
]}

机构：

[1] CNRS,AIME COTTON LAB,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF LUMINESCENCE | 1979年 / 18-9卷 / JAN期

关键词：

D O I：

10.1016/0022-2313(79)90258-8

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Frozen aqueous solutions of gadolinium chloride, bromide and perchlorate present the same optical absorption spectra. Comparison of Stark splittings of the frozen solutions compared to those of crystals indicates a single quasi-crystalline surrounding for the gadolinium ion with eight coordinated water molecules. Fluouescence exists and its intensity variation with temperature is discussed. © 1979.

引用

页码：891 / 896

页数：6

共 9 条

[1] SPECTRAL INTENSITIES OF TRIVALENT LANTHANIDES AND ACTINIDES IN SOLUTION .2. PM3+ SM3+ EU3+ GD3+ TB3+ DY3+ AND HO3+
CARNALL, WT
FIELDS, PR
RAJNAK, K
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) : 4412 - &
[2] CARNALL WT, 1968, J CHEM PHYS, V49, P4443, DOI 10.1063/1.1669894
[3] OPTICAL ABSORPTION SPECTRA OF GD3+-LAF3 AND GDCL3 .6H2O
CARNALL, WT
FIELDS, PR
SARUP, R
[J]. JOURNAL OF CHEMICAL PHYSICS, 1971, 54 (04) : 1476 - &
[4] OPTICAL-ABSORPTION SPECTRA OF ND3+ IONS TRAPPED IN ORDINARY ICE
COUTURE, L
LEPAILLIERMALECOT, A
[J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1975, 8 (05): : L67 - L72
[5] FRANKS F, 1972, WATER, V1, P535
[6] JEANLOUIS M, UNPUBLISHED
[7] CRYSTAL STRUCTURE OF GADOLINIUM TRICHLORIDE HEXAHYDRATE
MAREZIO, M
PLETTINGER, HA
ZACHARIASEN, WH
[J]. ACTA CRYSTALLOGRAPHICA, 1961, 14 (03): : 234 - &
[8] APPLICATION OF DOUBLE-DOUBLE EFFECT TO DETERMINATION OF LANTHANIDE AQUO-ION STRUCTURES
MIODUSKI, T
SIEKIERSKI, S
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1975, 37 (7-8): : 1647 - 1651
[9] ENERGY LEVELS OF GD3+ IN 5 HEXAGONAL CRYSTALS
SCHWIESOW, RL
CROSSWHITE, HM
[J]. JOURNAL OF THE OPTICAL SOCIETY OF AMERICA, 1969, 59 (05) : 592 - +

← 1 →