TRANSFORMATION OF BENZENE TO A POLYMER AFTER STATIC PRESSURIZATION TO 30 GPA

被引：121

作者：

PRUZAN, P ^{[1
]}

CHERVIN, JC ^{[1
]}

THIERY, MM ^{[1
]}

ITIE, JP ^{[1
]}

BESSON, JM ^{[1
]}

FORGERIT, JP ^{[1
]}

REVAULT, M ^{[1
]}

机构：

[1] LASIR,CNRS,LP2641,F-94230 THIAIS,FRANCE

来源：

JOURNAL OF CHEMICAL PHYSICS | 1990年 / 92卷 / 11期

关键词：

D O I：

10.1063/1.458278

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

After pressurization to 30 GPa, in a diamond anvil cell, benzene transforms, at room temperature, to a white solid which is stable at ambient pressure. We report here the infrared spectroscopy analysis performed under pressure and at ambient conditions. These preliminary results show that the transformation involves an opening of the benzene rings leading to a highly cross-linked polymer. © 1990 American Institute of Physics.

引用

页码：6910 / 6915

页数：6

共 35 条

[1] SOLID-STATE POLYMERIZATION OF CYANOACETYLENE INTO CONJUGATED LINEAR-CHAINS UNDER PRESSURE [J].