A STUDY ON HYDROGEN ENCAPSULATION IN CS2.5-ZEOLITE-A

被引:24
作者
YOON, JH [1 ]
HEO, NH [1 ]
机构
[1] KYUNGPOOK NATL UNIV,DEPT IND CHEM,TAEGU 702701,SOUTH KOREA
关键词
D O I
10.1021/j100191a049
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The numbers of hydrogen molecules encapsulated in the cavities of Cs2.5-zeolite A were calculated with respect to pressure as well as temperature, and the results were compared with known experimental data. The calculations were performed by the combined use of the statistical theory of the radial distribution function and the theory of the perfect 3-D lattice gas. The pressures and the temperatures used for the calculations ranged from 10 to 129 atm and from 373 to 623 K, respectively. The results indicated that these two theories were enough to reproduce the pressure-dependent experimental data which increase with increasing pressure at the pressures studied.
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页码:4997 / 5000
页数:4
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