PHOTOELECTRON AND THEORETICAL INVESTIGATIONS ON BISMUTH AND ANTIMONY PENTAMER ANIONS - EVIDENCE FOR AROMATIC STRUCTURE

被引：29

作者：

GAUSA, M

KASCHNER, R

LUTZ, HO

SEIFERT, G

MEIWESBROER, KH

机构：

[1] TECH UNIV DRESDEN,INST THEORET PHYS,D-01062 DRESDEN,GERMANY

[2] UNIV ROSTOCK,FACHBEREICH PHYS,D-18051 ROSTOCK,GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 230卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(94)01138-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We use photoelectron spectroscopy with UV laser light of hv approximate to 4 eV to investigate the electronic level structure of the bismuth and the antimony pentamer anion. Additionally we perform LCAO-LDA calculations for these clusters. We suggest the pentamers have a planar cyclic geometry, being aromatic under the 4n+2 Huckel rule, like benzene or cyclopentadienyl. The vertical detachment energies are calculated and show good agreement with experiment.

引用

页码：99 / 102

页数：4

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[2]

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