EVIDENCE FOR THE CHEMICAL NATURE AND ORDERING OF COBALTOCENE INTERCALATED IN CDPS3 USING SINGLE-CRYSTAL SOLID-STATE H-2 NMR-SPECTROSCOPY

被引：9

作者：

MASON, SJ ^{[1
]}

HEYES, SJ ^{[1
]}

OHARE, D ^{[1
]}

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 16期

关键词：

D O I：

10.1039/c39950001657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid state H-2 NMR spectra of single crystal samples of CdPS3{Co(eta-C5D5)(2)}(0.4) indicate the co-existence of both Co(eta-C5D5)(2) and [CO(eta-C5D5)(2)](+) between the CdPS3 layers; all the metallocene guest molecules reside in ordered domains within the ab-plane of the host lattice at a 90 degrees angle to each other, and with their principal C-5-symmetry axes parallel to the layers of the host lattice.

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页码：1657 / 1658

页数：2

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