PHOTO-CHEMICAL AND THERMAL ISOMERIZATIONS OF 1-METHOXYALLYL CATIONS - FURTHER PHOTOISOMERIZATION PATHWAY OF PROTONATED ENONES

被引：8

作者：

CHILDS, RF

HAGAR, ME

机构：

[1] Department of Chemistry, McMaster University, Hamilton, Ontario

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 04期

关键词：

D O I：

10.1021/ja00498a054

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There have been several investigations into the photoisomerizations of protonated unsaturated carbonyl compounds in strong acid solutions and a variety of molecular rearrangements of these systems have been described.1, 2 We report here that a further, fundamental type of reaction can occur, namely photoisomerism about the carbon-oxygen partial double bond.© 1979, American Chemical Society. All rights reserved.

引用

页码：1052 / 1053

页数：2

共 17 条

[1] PI-DONATING ABILITIES OF SULFUR AND OXYGEN - COMPARATIVE QUANTUM CHEMICAL INVESTIGATION OF STATIC AND DYNAMIC PROPERTIES AND GAS-PHASE ACIDITIES OF +CH2OH AND +CH2SH [J].