THIOLATE ANION AS A NUCLEOPHILE .9. REACTIONS OF SOME FLUOROAROMATICS

被引:18
作者
PEACH, ME
RAYNER, ES
机构
[1] Chemistry Department, Acadia University, Wolfville
关键词
D O I
10.1016/S0022-1139(00)81580-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reactions of some halogenoaromatic compounds, mainly fluoroaromatics C6FxH6-x with the methanethiolate anion have been studied in DMF or an HMPA/THF mixture. Complete replacement of fluorine occurred forming C6(SMe)xH6-x. Attempts to prepare C6(SEt)6 and compounds such as C6(SEt)2(SMe)4 are described. Other new compounds isolated included C6(SMe)5SH and C6F2(SMe)2(SEt)2. Details of the spectra, particularly NMR, are given. © 1979.
引用
收藏
页码:447 / 454
页数:8
相关论文
共 20 条