THIOLATE ANION AS A NUCLEOPHILE .9. REACTIONS OF SOME FLUOROAROMATICS

被引：18

作者：

PEACH, ME

RAYNER, ES

机构：

[1] Chemistry Department, Acadia University, Wolfville

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1979年 / 13卷 / 05期

关键词：

D O I：

10.1016/S0022-1139(00)81580-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of some halogenoaromatic compounds, mainly fluoroaromatics C6FxH6-x with the methanethiolate anion have been studied in DMF or an HMPA/THF mixture. Complete replacement of fluorine occurred forming C6(SMe)xH6-x. Attempts to prepare C6(SEt)6 and compounds such as C6(SEt)2(SMe)4 are described. Other new compounds isolated included C6(SMe)5SH and C6F2(SMe)2(SEt)2. Details of the spectra, particularly NMR, are given. © 1979.

引用

页码：447 / 454

页数：8

共 20 条

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