METHACRYLIC-ACID SYNTHESIS .1. CONDENSATION OF PROPIONIC-ACID WITH FORMALDEHYDE OVER ALKALI-METAL CATION ON SILICA CATALYSTS

被引：39

作者：

BAILEY, OH

MONTAG, RA

YOO, JS

机构：

[1] Amoco Research Center, Naperville, IL 60566

来源：

APPLIED CATALYSIS A-GENERAL | 1992年 / 88卷 / 02期

关键词：

ALKALI METAL CATION; CONDENSATION; FORMALDEHYDE; PROPIONIC ACID; SILICA;

D O I：

10.1016/0926-860X(92)80213-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alkali metal cations supported on silica are effective base catalysts for the production of methacrylic acid via the condensation of propionic acid with formaldehyde. Activity and selectivity are dependent on the choice of alkali metal cation and increase in the order Li < Na < K < Cs. Activity also increases with increasing cation loading. A model for the dependence of product selectivity on cation loading is proposed.

引用

页码：163 / 177

页数：15

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