IMPROVING ENANTIOSELECTIVITY BY USING A MONO-SULFONATED DIPHOSPHINE AS LIGAND FOR HOMOGENEOUS IMINE HYDROGENATION

被引：79

作者：

LENSINK, C ^{[1
]}

DEVRIES, JG ^{[1
]}

机构：

[1] DSM RES & PATENTS,DEPT CHEM PROD INTERMEDIATES,POB 18,6160 MD GELEEN,NETHERLANDS

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(00)80199-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Rhodium catalysed hydrogenation of acetophenone N-benzylimine using mono-sulphonated (2S,4S)-bis-(diphenylphosphino) pentane as ligand gives the corresponding amine with 94% e.e., whereas use of the di-sulphonated ligand yields product with 2% e.e.

引用

页码：235 / 238

页数：4

共 14 条

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