SOLVENT EFFECTS ON THE SOLUBILITIES OF REFERENCE ELECTROLYTES

被引：6

作者：

PIRKLBAUER, M ^{[1
]}

GRITZNER, G ^{[1
]}

机构：

[1] JOHANNES KEPLER UNIV,INST CHEM TECHNOL ANORGAN STOFFE,A-4040 LINZ,AUSTRIA

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1993年 / 22卷 / 07期

关键词：

REFERENCE ELECTROLYTES; SOLVENT EFFECTS; SOLUBILITIES OF BIS(BIPHENYL)CHROMIUM TETRAPHENYLBORATE; TETRAPHENYLARSONIUM TETRAPHENYLBORATE;

D O I：

10.1007/BF00646780

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solubilities of bis(biphenyl)chromium(I) tetraphenylborate were measured in 25, solubilities of tetraphenylarsonium tetraphenylborate in nine and solubilities of bis(biphenyl)chromium(0) in seven nonaqueous solvents. Linear dependences of the pK(s)-values for these compounds as well as the pK(s) values for tetraphenylstibonium tetraphenylborate, tetraphenylmethane and tetraphenylgermane were observed. The relations between the pK(s)-values of the above mentioned compounds and solvent parameters as well as solvent structure are discussed.

引用

页码：585 / 599

页数：15

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