SYNTHESIS OF MONODEOXYCALIX[4]ARENE AND ITS DIMER STRUCTURE IN SOLUTION

被引：49

作者：

FUKAZAWA, Y

DEYAMA, K

USUI, S

机构：

[1] Department of Chemistry, Faculty of Science, Hiroshima University, Higashi-Hiroshima

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 39期

关键词：

D O I：

10.1016/0040-4039(92)89036-C

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Monodeoxycalix[4]arene (3) has been synthesized by a stepwise condensation method. It forms dimer in solution, the structure of which has an arrangement of the two cone of 3 facing the respective narrower rim with each other. A cyclic hydrogen bonding array of six hydroxyl groups in the dimer was suggested from the thermodynamic parameters of the monomer-dimer equilibrium.

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页码：5803 / 5806

页数：4

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