HIGHLY STEREOSELECTIVE ADDITION OF ALKYLCOPPER REAGENTS TO N-ACYLIMINIUM IONS - ENANTIOSELECTIVE SYNTHESIS OF TRANS-2-BUTYL-5-HEPTYLPYRROLIDINE

被引：56

作者：

SKRINJAR, M ^{[1
]}

WISTRAND, LG ^{[1
]}

机构：

[1] UNIV LUND,CTR CHEM,POB 124,S-22100 LUND,SWEDEN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(00)88878-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition of RCu, BF3 to the electrochemically prepared α-methoxy proline ester 1 has been shown to be highly trans (≥96%) selective. This reaction has been developed into an enantioselective synthesis of the ant trail feromone trans-2-butyl-5-heptylpyrrolidine. © 1990.

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页码：1775 / 1778

页数：4

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