Stereochemistry of Photosolvolysis of Quaternary Benzylammonium Salts in Hydroxylic Solvents

被引：14

作者：

Lillis, Veronica ^{[1
]}

McKenna, James ^{[1
]}

McKenna, Jean M. ^{[1
]}

Williams, Ian H. ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1974年 / 12期

关键词：

D O I：

10.1039/c39740000474

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photosolvolysis of optically active 1-phenylethyltrimethylammonium iodide in water or methanol is characterised by extensive racemisation accompanied by some net configurational inversion; the quaternary salt recovered from incomplete reaction in water has fully retained configuration at carbon, while analogous retention at nitrogen is observed in similar experiments in methanol with appropriately chosen related salts.

引用

页码：474 / 474

页数：1

共 6 条

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[5] OPTICALLY ACTIVE PHENYLMETHYLCARBINYL ETHERS
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ELLIOTT, SP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (26) : 7550 - &

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