THE SYNTHESIS AND POLYMERIZATION OF SOME NEW 1,1'-SUBSTITUTED VINYLFERROCENES OF THE TYPE [FE(ETA-5-C5H4X)(ETA-5-C5H4(CH=CH2))] (X = CL, BR, CN OR CONH2)

被引：2

作者：

AFEWORKI, S ^{[1
]}

BAKER, PK ^{[1
]}

PARRI, OL ^{[1
]}

DSILVA, C ^{[1
]}

机构：

[1] UNIV WALES,DEPT CHEM,INST MOLEC & BIOMOLEC ELECTR,BANGOR LL57 2UW,GWYNEDD,WALES

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 431卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)83287-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some substituted vinylferrocenes of the type [Fe(eta-5-C5H4X){eta-5-C5H4(CH=CH2)}] (X = Cl, Br, CN or CONH2) have been prepared. Free radical polymerisation of substituted vinylferrocenes [Fe(eta-5-C5H4X)(eta-5-C5H4(CH=CH2)}] (X = Cl, Br or CN) with AIBN (AIBN = 2,2'-azobis-2-methylpropionitrile) as initiator gave polymers with molecular weights ranging from 13,700 (X = Cl) to 44,300 (X = CN).

引用

页码：81 / 86

页数：6

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