SYNTHESIS, CHARACTERIZATION AND REACTIONS OF PHENYLANTIMONY(III) AMIDES, PH(N)SB(NR2)3-N(N = 1 AND 2)

被引：2

作者：

SINGHAL, K

机构：

[1] Chemistry Department, Lucknow University

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1993年 / 23卷 / 08期

关键词：

D O I：

10.1080/15533179308016692

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of three-coordinated phenylantimony-(III) amides of the type PhnSb(NR2)3-n (n=1 and 2) where HNR2 = 6-chloro-5-methoxy, 6-methoxy-5-bromo, 7-chloro, 5-methoxy-6-bromo, 5-methoxy and 5-bromoisatin has been synthesized and characterized by elemental analyses, melting points, IR spectra, conductivity and molecular weight measurements. These amides are hydrolytically unstable but unaffected by ethanol and CS2. However, PhNCO was found to add across the Sb-N bond. Bromine, TeCl4 and acetic acid cleave the Sb-N bond in preference to the Sb-phenyl bond(s).

引用

页码：1363 / 1377

页数：15

共 16 条

[1]

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[2]

GUPTA R, 1985, INDIAN J CHEM A, V24, P752

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