DUAL PATHWAYS FOR MANGANESE CATALYSIS OF OLEFIN OXIDATION WITH ALKYL HYDROPEROXIDES

被引：114

作者：

SRINIVASAN, K

PERRIER, S

KOCHI, JK

机构：

[1] Univ of Houston, Houston, TX, USA, Univ of Houston, Houston, TX, USA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1986年 / 36卷 / 03期

基金：

美国国家科学基金会;

关键词：

CATALYSTS; -; Materials; OLEFINS; Oxidation; OXIDES; Applications;

D O I：

10.1016/0304-5102(86)85086-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic oxidation of various olefins with t-butyl hydroperoxide as the terminal oxidant is effectively carried out with cationic manganese(III) complexes of the salen ligand left bracket N,N prime -ethylenebis(salicylideneaminato) right bracket in the presence of pyridine or imidazole as the cocatalyst. Two concurrent processes have been identified with cyclohexene as the olefinic substrate, which affords both cyclohexenyl t-butyl peroxide and cyclohexene oxide within 5 min at 25 degree C in acetonitrile solutions.

引用

页码：297 / 317

页数：21

共 56 条

[1] HYDROPEROXIDE OXIDATIONS CATALYZED BY METALS .4. MOLYBDENUM HEXACARBONYL CATALYZED EPOXIDATION OF 1-OCTENE [J].