IONS [CH3S]+ [C2H5S]+ AND [CH3O]+ FORMED BY ELECTRON-IMPACT

被引：31

作者：

AMOS, D

GILLIS, RG

OCCOLOWI.JL

PISANI, JF

机构：

[1] Australian Defence Scientific Service, Defence Standards Laboratories, Maribyrnong, Victoria

[2] Lilly Research Laboratories, Indianapolis, Indiana

来源：

ORGANIC MASS SPECTROMETRY | 1969年 / 2卷 / 02期

关键词：

D O I：

10.1002/oms.1210020206

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mass spectra of deuterated species shows that both the isomeric ions [CH2SH]+ and [CH3S]+ are formed in the ratio 2:1 from CH3SH; the ions [CH3CHSH]+ and [CH3CH2S]+ in the ratio 0·8:1 from CH3CH2SH; and [CH2OH]+ and [CH3O]+ in the ratio 6·7:1 from methanol. The heats of formation of [CH3S]+ and [C2H5S]+ are of the order of 222 and 203 Kcal.mole−1 respectively. The isomeric ions cannot be distinguished on thermodynamic grounds. Copyright © 1969 John Wiley & Sons, Ltd.

引用

页码：209 / &

共 6 条

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