STUDIES ON BICYCLONONANES .7. REACTIONS OF (1-BICYCLO[3,3,1]-NONYL)METHYL AND RELATED IONS

被引:18
作者
GRAHAM, SH
JONAS, DA
机构
[1] Edward Davies Chemical Laboratory, Aberystwyth
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 02期
关键词
D O I
10.1039/j39690000188
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The solvolyses of esters of 1-hydroxymethylbicyclononane, 5-hydroxymethylmethylenecyclo-octane, and 1-methyl-5-hydroxymethylcyclo-octene are described, together with the deaminations of the corresponding amines. The occurrence of 1,3-hydride shifts is reported, and the implications of the results, as regards the π-route to bicyclic molecules, are discussed.
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页码:188 / &
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