SYNTHESIS AND OXIDATION OF 1,2-LAMBDA-5-AZAPHOSPHININES

被引：11

作者：

BEDEL, C ^{[1
]}

FOUCAUD, A ^{[1
]}

机构：

[1] UNIV RENNES 1,CNRS,RECH CHIM STRUCT GRP,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 23期

关键词：

1,5-LAMBDA-5-AZAPHOSPHININES; NON-SENSITIZED OXIDATION; PHOSPHINE OXIDES; ISOMERIZATION;

D O I：

10.1016/S0040-4039(00)78800-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,2-lambda-5-azaphosphinines are prepared from l-t.butyl 1,2-dihydro 1,2-lambda-3-azaphosphinines by methylation on phosphorus atom, thermolysis of the resulting phosphonium salts and treatment with potassium carbonate. The 1,2-lambda-5-azaphosphinines, oxidized on exposure to air give phosphine oxides.

引用

页码：2619 / 2620

页数：2

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