CATIONIC CONDUCTIVITY OF BLEND COMPLEXES COMPOSED OF POLY[OLIGO(OXYETHYLENE)METHACRYLATE] AND THE ALKALI-METAL SALTS OF POLY(SULFOALKYL METHACRYLATE)

被引：25

作者：

ZHANG, SS ^{[1
]}

DENG, ZH ^{[1
]}

WAN, GX ^{[1
]}

机构：

[1] ACAD SINICA,CHENGDU INST ORGAN CHEM,CHENGDU 610015,PEOPLES R CHINA

来源：

POLYMER JOURNAL | 1991年 / 23卷 / 02期

关键词：

COMB-SHAPED POLYETHER; POLYMERIC SALT; BLEND COMPLEX; CATIONIC CONDUCTIVITY;

D O I：

10.1295/polymj.23.73

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two kinds of alkali metal salts of poly(sulfoalkyl methacrylate)s (PSAMM) were prepared, with which the blend complexes of poly[oligo(oxyethylene) methacrylate] (PMEO(n)) were formed. These blend complexes contain neither organic plasticizer nor low molecular weight Li-salt and are considered to be single-cationic conductors which are characterized by stable dc ionic conductivity. Cationic conductivity is deeply influenced by the glass transition temperature, cation species, polar group (acrylonitrile), the concentration of polymeric salts, and the size of side-group in PSAMM. An optimum Li+-ionic conductivity of 1.1 x 10(-6) S cm-1 at 25-degrees-C is obtained for the blend complex P(0.6MEO18-0.4AN)/P(0.5SHMLi-0.5AN) (AN, acrylonitrile; SHMLi, lithium sulfohexyl methacrylate) with O/Li = 72.

引用

页码：73 / 78

页数：6

共 10 条

[1] IONIC CONDUCTIVITIES FOR POLY(ETHYLENE OXIDE) COMPLEXES WITH LITHIUM-SALTS OF MONOBASIC AND DIBASIC ACIDS AND BLENDS OF POLY(ETHYLENE OXIDE) WITH LITHIUM-SALTS OF ANIONIC POLYMERS
BANNISTER, DJ
DAVIES, GR
WARD, IM
MCINTYRE, JE
[J]. POLYMER, 1984, 25 (09) : 1291 - 1296
[2] CAMPBELL KN, 1955, ORG SYNTH COLL, V3, P446
[3] COWIE JMG, 1985, POLYM COMMUN, V26, P298
[4] CHLORIDE-ION CONDUCTIVITY IN A PLASTICIZED QUATERNARY AMMONIUM POLYMER
HARDY, LC
SHRIVER, DF
[J]. MACROMOLECULES, 1984, 17 (04) : 975 - 977
[5] LENEST JF, 1988, BR POLYM J, V3, P20
[6] OHNO H, 1908, J MACROMOL SCI CHE A, V26, P511
[7] PILIPPE G, 1986, POLYM COMMUN, V27, P16
[8] ION-TRANSPORT IN SOLVENT-FREE POLYMERS
RATNER, MA
SHRIVER, DF
[J]. CHEMICAL REVIEWS, 1988, 88 (01) : 109 - 124
[9] SHEETZ DP, 1964, Patent No. 3147301
[10] XU K, S POLYM SCI CHENGDU, P591

← 1 →