RESOLUTION OF AMINO-ACIDS IN A MIXTURE OF 2-METHYL-2-PROPANOL WATER (19/1) CATALYZED BY ALCALASE VIA IN-SITU RACEMIZATION OF ONE ANTIPODE MEDIATED BY PYRIDOXAL 5-PHOSPHATE

被引：40

作者：

CHEN, ST ^{[1
]}

HUANG, WH ^{[1
]}

WANG, KT ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10098,TAIWAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 25期

关键词：

D O I：

10.1021/jo00104a007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Procedures for the conversion of a racemic amino acid into the L-enantiomer by the alcalase-catalyzed resolution of the amino acid ester in 2-methyl-2-propanol/water (19:1) simultaneously with the pyridoxal 5-phosphate-catalyzed racemization of the unhydrolyzed antipode have been developed.

引用

收藏

页码：7580 / 7581

页数：2

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