A NEW CHIRAL CYCLOPHANE DERIVED FROM 1,1'-BINAPHTHOL AND BENZYLVIOLOGEN

被引：7

作者：

DENG, NL ^{[1
]}

MARWAHA, VR ^{[1
]}

GARCIA, ME ^{[1
]}

BENESI, A ^{[1
]}

MALLOUK, TE ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 42期

关键词：

D O I：

10.1016/0040-4039(95)01593-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new chiral cyclophane, with a binding cavity defined by the 1,1'-binaphthyl ''minor groove'' and a strongly pi-accepting 4,4'-bipyridinium dication, has been synthesized. It self-associates in solution (K = (4.1 +/- 1.6) x 10(2) M(-1)), and forms charge-transfer complexes with strong pi-electron donors.

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页码：7599 / 7602

页数：4

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