BIOSYNTHESIS OF NATURAL-PRODUCTS .2. SYNTHESES OF C-14-LABELED OR H-3-LABELED ENT-KAUR-16-ENE DERIVATIVES OXYGENATED AT C-7, OR AT C-7 AND C-15, FROM EPICANDICANDIOL

被引：4

作者：

FUJITA, T ^{[1
]}

TAKAO, S ^{[1
]}

FUJITA, E ^{[1
]}

机构：

[1] KYOTO UNIV,INST CHEM RES,UJI,KYOTO 611,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 04期

关键词：

D O I：

10.1039/p19790000910

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

ent-Kaur-16-en-7α-ol (12a), ent-kaur-16-en-7-one (14a), ent-kaur-16-en-7β-ol (15a), ent-15-oxokaur-16-en-7α-ol (22a), and enr-kaur-16-ene-7,15-dione (23a), and the labelled compounds (12b), (14b), (14c), (15b), (22b), (23b), and (23c), which are required for the investigation on the biosynthetic route from ent-kaur-16-ene (1) into enmein (3) and oridonin (4), were synthesised from epicandicandiol (5).

引用

页码：910 / 914

页数：5

共 7 条

[1] GARRYFOLINE-CUAUCHICHICINE REARRANGEMENT - A STUDY OF MECHANISM IN (-)-KAURENOLS [J].